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N-Heterocyclic Carbenes in Transition Metal Catalysis
It was only in the early 1990s that carbenes with the carbene carbon being incorporated in a nitrogen containing heterocycle (N-heterocyclic carbenes or NHCs) were found to be stable enough to be isolated. Since the first report on the application of NHCs as ligands in transition metal catalysis in 1995, NHC have found numerous applications and have been established as a versatile and indispensable class of ligands. For many reactions like metathesis or cross-coupling reactions NHCs have often become the ligands of choice, allowing otherwise difficult transformations. In this book leading experts have surveyed major areas of application of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. This compilation is rounded out by an introductory chapter and a chapter dealing with synthetic routes to NHC metal complexes.
Multiple Bonds between Metal Atoms
The 3rd edition of the Multiple Bonds between Metal Atoms deals with one of the most active fields of inorganic chemistry … . It presents an extensive, critical review and discussion of preparations, reactions, bonding, and physical properties of more than 4000 compounds … heartily recommend it to inorganic and materials chemists, and to all scientists concerned with the synthesis, spectroscopy, and structures of transition-metal compounds. It also belongs in academic, industrial, and government research libraries.
Metals in Society and in the Environment : A Critical Review of Current Knowledge on Fluxes, Speciation, Bioavailability and Risk for Adverse Effects of Copper, Chromium, Nickel and Zinc
In 2002, the Swedish Metal Information Task Force (MITF) engaged the Environmental Research Group (MFG) to update previous monographs on copper, zinc and major alloying metals (such as chromium, nickel and molybdenum) in society and in the environment. This book presents new results on metal fluxes from society to the environment, on metal speciation in water, soil and sediment, and its interpretation in terms of mobility, biological uptake and toxicity. The scientific fundamentals of new approaches, like the Acid Volatile Sulphide (AVS) concept to predict metal bioavailability in sediments, and the Biotic Ligand Model (BLM) to calculate the toxicity of metals to aquatic organisms, are critically evaluated, with a focus on copper, nickel, zinc, and, in part, chromium.
Metal Catalyzed Reductive C-C Bond Formation : A Departure from Preformed Organometallic Reagents
The prototypical catalytic reductive C–C bond formations, the Fischer-Tropsch reaction [1] and alkene hydroformylation [2], were discovered in 1922 and 1938, respectively [3,4]. These processes, which involve reductive coupling to carbon monoxide, have long been applied to the industrial manufacture of commodity chemicals [5]. Notably, alkene hydroformylation, also known as the oxo-synthesis, has emerged as the largest volume application of homogeneous metal catalysis, accounting for the production of over 7 million metrictons of aldehyde annually. Despite the impact of these prototypical reductive C–C bond formations, this field of research lay fallow for several decades.
Hot cracking phenomena in welds II
This is the second in a series of compendiums devoted to weld hot cracking phenomena, where this subject has been further scrutinized, bringing to bare the most current thoughts on this complex and diverse subject. With 22 technical papers in total, this book is divided in such a way that specific classifications of hot cracks are examined in detail, including solidification, liquation, and ductility dip cracking. The first chapter looks at solidification cracking theory, applying the most modern approaches to modelling weld solidification. Also provided here is a comprehensive review of cracking models. This is followed by two chapters characterizing solidification cracking behaviour for specific alloy systems: ferrous plus nickel-based alloys and aluminium alloys, respectively. The fourth chapter considers liquation cracking in ferrous alloys, and the fifth examines ductility-dip cracking.
Heterocycles from Transition Metal Catalysis : Formation and Functionalization
The book provides a representative selection of transition metal catalysed reactions, transformations that are relevant in heterocyclic chemistry. In this way, the authors provide a useful resource for members of the academic community looking for a textbook as well as industrial chemists in search of a reference book. This book is an invaluable resource for synthetic chemists, medicinal chemists, and those more generally interested in applied catalysis.
Graphs, networks and algorithms ; 3rd ed.
The third edition of this standard textbook contains additional material: two new application sections (on graphical codes and their decoding) and about two dozen further exercises (with solutions, as throughout the text). Moreover, recent developments have been discussed and referenced, in particular for the travelling salesman problem. The presentation has been improved in many places (for instance, in the chapters on shortest paths and on colorings), and a number of proofs have been reorganized, making them more precise or more transparent.
Graphs, networks and algorithms ; 2nd ed.
This book have a chapter on the network simplex algorithm and a section on the five color theorem; this also necessitated some changes in the previous order of the presentation (so that the numbering differs from that of the first edition,beginning with Chapter 8). In addition to this, numerous smaller changes and corrections have been made and several recent developments have been discussed and referenced. There are also several new exercises.
Draughtsmen, Botanists and Nature : The Construction of Eighteenth-Century Botanical Illustrations
This book is the first in-depth study of eighteenth-century botanical illustrations, and its findings offer a completely new insight into the working practices of the botanists and scientific draughtsmen of this period. The author describes the different production stages of these illustrations, traces their uses by means of the private correspondence of participants and the documentation of the learned societies and academies, and explores their visual language, with particular emphasis placed on the difficult issue of colour. Finally, and for the first time, the author presents a convincing description of how these botanical illustrations developed.
Location Theory : A Unified Approach
Although modern location theory is now more than 90 years old, the focus of researchers in this area has been mainly problem oriented. However, a common theory, which keeps the essential characteristics of classical location models, is still missing. This monograph addresses this issue. A flexible location problem called the Ordered Median Problem (OMP) is introduced. For all three main subareas of location theory (continuous, network and discrete location) structural properties of the OMP are presented and solution approaches provided. Numerous illustrations and examples help the reader to become familiar with this new location model.
Bioorganometallic Chemistry
Bioorganometallic Chemistry has become a mature area of science and is comprehensively covered by leading experts in this book. Naturally occuring bioorganometallic complexes, such as vitamin B12 and recently discovered iron and nickel hydrogenases, including a possible role of the latter in the geochemical theory of the origin of life, are considered.
