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Electron crystallography : Novel approaches for structure determination of nanosized materials
During the last decade we have been witness to several exciting achievements in electron crystallography. This includes structural and charge density studies on organic molecules complicated inorganic and metallic materials in the amorphous, nano-, meso- and quasi-crystalline state and also development of new software, tailor-made for the special needs of electron crystallography. This volume comprises the proceedings of the NATO Advanced Study Institute on Electron Crystallography: Novel Approaches for Structure Determination of Nanosized Materials, Erice, Italy, 10 - 24 June 2004
Electrochemistry of Immobilized Particles and Droplets
Immobilizing particles or droplets on electrodes is a novel and most powerful technique for studying the electrochemical reactions of three-phase systems. It gives access to a wealth of information, ranging from quantitative and phase analysis to thermodynamic and kinetic data of electrode processes. Three-phase electrodes with immobilized droplets provide information on the electrochemistry of redox liquids and of compounds dissolved in inert organic liquids. Such measurements allow the determination of the Gibbs energies of the transfer of cations and anions between immiscible solvents, and thus make it possible to assess the hydrophobicity of ions – a property that is of great importance for pharmaceutical applications, biological studies, and for many fields of chemistry.The monograph gives, for the first time, a comprehensive overview of the results published in more than 300 papers over the last 15 years. The experiments are explained in detail, applications from many different fields are presented, and the theoretical basis of the systems is outlined.
Electrochemical Dictionary
The Electrochemical Dictionary provides up-to-date, broad and authoritative coverage of the specific terms most used in electrochemistry and its related fields, including relevant areas of physics and engineering. This modern compendium will be an indispensable source of information for scientists, engineers, and technical staff active in all fields of electrochemistry. The more than 2.770 entries have been written by a distinguished panel of eminent electrochemists. Each entry supplies a clear and precise explanation of the term and provides references to the most useful reviews, books and original papers to enable readers to pursue a deeper understanding if so desired.
Electroanalytical shemistry : Principles, best practices, and case studies
Written for undergraduate majors in chemistry and chemical engineering, this book teaches the basic principles of electroanalytical chemistry and illustrates best practices through the use of case studies of organic reactions and catalysis using voltammetric methods and of the measurement of clinical and environmental analytes by potentiometric techniques. It provides insight beyond the field of analysis as students address problems arising in many areas of science and technology. The book also emphasizes electrochemical phenomena and conceptual models to help readers understand the influence of experimental conditions and the interpretation of results for common potentiometric and voltammetric methods.
Efficiency in Natural Product Total Synthesis
Uniting the key organic topics of total synthesis and efficient synthetic methodologies, this book clearly overviews synthetic strategies and tactics applied in total synthesis, demonstrating how the total synthesis of natural products enables scientific and drug discovery. • Focuses on efficiency, a fundamental and important issue in natural products synthesis that makes natural product synthesis a powerful tool in biological and pharmaceutical science • Describes new methods like organocatalysis, multicomponent and cascade reactions, and biomimetic synthesis
Digital Economy and Social Design
The advent of the digital economy has the potential to dramatically change the conventional interrelationships among individuals, enterprises and society. There can be little doubt that to achieve vigorous socioeconomic developments in the 21st century, people will have to aggressively use information technology to boost innovation and to organically link the results of that innovation to solutions to global environmental issues and social challenges such as the opportunity divide. We are responsible for taking advantage of the opportunities opened up by the digital economy and for turning those opportunities into things that reflect our values and goals. The book examines the overall impact of the digital economy and the development of a practical institutional design.
Digital Design of Nature : Computer Generated Plants and Organics
The reproduction of nature via computer has fascinated scientists in computer graphics and artists ever since synthetic imaging was thought possible. This book illustrates and exemplifies methods for the creation of artificial plant models, and the application of these methods within areas such as simulation, virtual reality, botany, landscaping, and architecture.The models are combined to create gardens, parks, and even entire landscapes.The range of creating representational forms reaches from deceptively authentic looking pictures to abstract presentations. In addition, with similar methods organic objects can be produced, changed, and animated.
Detection and Disposal of Improvised Explosives
It including: Methods of detection of Improvised Explosives (IE). Methods of detection of Improvised explosives devices (IED). Disposal and safe handling of ID and IED. The treatment of detection methods may be divided in the following groups: Overview about the different methods; Trace- and vapor detection; Electromagnetic methods; Neutron methods; Laser techniques. Because of different definitions of Improvised Explosives the parti- pants of the workshop agreed after some discussions with the following definition: An Improvised Explosive (IE) can be any chemical compound or mixture capable of an explosive reaction. They are normally easily prepared by a knowledgeable layman under simple conditions. Components of IE are typically inorganic salts containing molecular bound oxygen like nitrates, chlorates or perchlorates etc. or organic compounds with nitro-, nitami- or nitrate-groups or peroxides. Admixtures of military or commercial explosive materials are also used. From the chemical point of view IE can be divided into the following types: Salts containing chemical groups with oxygen (like nitrates, chlorates or perchlorates etc.) in mixtures with combustible substances like carbon-hydrogen compounds.
Deep eutectic polvents : Synthesis, properties, and applications
Deep Eutectic Solvents contains a comprehensive review of the use of deep eutectic solvents (DESs) as an environmentally benign alternative reaction media for chemical transformations and processes. The contributors cover a range of topics including synthesis, structure, properties, toxicity and biodegradability of DESs. The book also explores myriad applications in various disciplines, such as organic synthesis and (bio)catalysis, electrochemistry, extraction, analytical chemistry, polymerizations, (nano)materials preparation, biomass processing, and gas adsorption.
Dangerous Pollutants (Xenobiotics) in Urban Water Cycle
The book focused on evaluation of impact of xenobiotics in the whole Urban Water Cycle are an interdisciplinary task which has a rising concern these days. Xenobiotics includes both inorganic elements like heavy metals, metalloids and man-made organic compounds such as pesticides, surfactants, solvents, fragrances, flavours, and pharmaceuticals as well as endocrine dis- pters.
Current Developments in Solid-state Fermentation
Over the period of last two decades, there has been significant resurgence in solid-state fermentation due to the numerous benefits it offers, especially in the engineering and environmental aspects. SSF has shown much promise in the development of several bioprocesses and products. This resurgence gained further momentum during the last 5-6 years with the developments in fundamental and applied aspects. A good deal of information has been generated in published literature and patented information. Several commercial ventures have come up based on SSF in different parts of the world. The contents are organized into four parts: Part 1 deals with the General and Fundamentals aspects of SSF; Part 2 deals with the production of bulk chemicals and products such as enzymes, organic acids, spores and mushrooms in SSF; Part 3 is on the use of SSF for specialty chemicals such as gibberellic acid, antibiotics and other pharmaceutically valuable secondary metabolites, pigments, and aroma compounds; Part 4 deals with the use of SSF miscellaneous application such as SSF for food and feed applications, agro-industrial residues as substrates in SSF and the production of silage and vermicompost.
Creative Chemical Sensor Systems
Schrader has compiled an excellent set of articles that present a current snapshot of chemical sensing utilizing state-of-the-art approaches ranging from combinatorial receptor libraries to artificial membrane pores. This volume is an excellent read for the budding and seasoned bioorganic chemist, chemical biologist, or supramolecular chemist as well as for those in allied fields who wish to apply emerging chemical techniques to solve current problems in chemical sensing.This book provides an overview of recent creative new approaches which use chemical means of detection and quantification of important analytes. Creative chemical sensor systems is a rapidly growing subject.
Contributions to Ubiquitous Computing
This book puts the larger vision of ubiquitous computing in the context of today’s mobile and distributed computing systems and presents innovative solutions at all system layers ranging from hardware over vertical and horizontal infrastructure services and novel middleware techniques to various types of application software. Some chapters address core properties of ubiquitous applications including mobility, self-healing and self-organisation of both technical and social-technical systems. Other contributions deal with common facilities like secure e-payment or semantic web techniques and business solutions like wireless asset management or e- maintenance. Distributed systems management with self-monitoring capabilities, Internet congestion control, and novel security solutions coping with denial of service attacks against mobile agent systems and software- and hardware-based data encryption methods are further topics addressed.
Contemporary Metal Boron Chemistry I : Borylenes, Boryls, Borane Sigma-Complexes, and Borohydrides
With information that will remain valid for years, this series presents critical reviews of the present position and future trends in modern research into chemical structure and bonding. It features concise reports, each written by world-renowned experts.
Computational Materials Chemistry : Methods and Applications
As a result of the advancements in algorithms and the huge increase in speed of computers over the past decade, electronic structure calculations have evolved into a valuable tool for characterizing surface species and for elucidating the pathways for their formation and reactivity. It is also now possible to calculate, including electric field effects, STM images for surface structures. To date the calculation of such images has been dominated by density functional methods, primarily because the computational cost of - curate wave-function based calculations using either realistic cluster or slab models would be prohibitive. DFT calculations have proven especially valuable for elucidating chemical processes on silicon and other semiconductor surfaces. However, it is also clear that some of the systems to which DFT methods have been applied have large non-dynamical correlation effects, which may not be properly handled by the current generation of Kohn-Sham-based density functionals. For example, our CASSCF calculations on the Si(001)/acetylene system reveal that at some geometries there is extensive 86 configuration mixing. This, in turn, could signal problems for DFT cal- lations on these systems.
Comets and the Origin and Evolution of Life
Nine years after the publication of Comets and the Origin and Evolution of Life, one of the pioneering books in Astrobiology, this second edition revisits the role comets may have played in the origins and evolution of life. Recent analyses of Antarctic micrometeorites and ancient rocks in Australia and South Africa, the continuing progress in discovering complex organic macromolecules in comets, protostars and interstellar clouds, new insights into organic synthesis in comets, and numerical simulations of comet impacts on the Earth and other members of the solar system yield a spectacular wealth of new results.
Comets : Nature, Dynamics, Origin, and their Cosmogonical Relevance
The book covers the most recent ideas about the nature and dynamics of comets, including a thorough discussion on Oort cloud dynamics which has not received due attention in other books on the subject. It also discusses the most relevant aspects of the physics and chemistry of comet nuclei, highlighting their importance as relics of the protoplanetary disk and, perhaps, as carriers of water and organics that permitted the development of life on Earth. The book contains several tables with useful data, and an ample bibliography covering the most recent work as well as some historical key contributions to the subject. It may be suitable as a textbook for graduate students with some basic knowledge of celestial mechanics and astrophysics, as well as a consult book for comet researchers, or researchers from other related fields willing to start working on comets, or get an updated view of the subject.
Combinatorial Chemistry on Solid Supports
In this volume, state-of-the-art solid-phase synthesis is presented from different angles. Ranging from methodology development to application in the synthesis of complex native and designed structures, a complete overview is presented. We are confident that addressing the fascinating interface between chemistry and biology is only possible by innovative methods in both disciplines. Combinatorial chemistry is surely one of these.This book, written by an international group of renowned experts in their respective field, covers recent advances in important topics regarding combinatorial chemistry on solid supports
Collagen : Primer in Structure, Processing and Assembly
This volume of Topics in Current Chemistry is an attempt to update and compile the biochemical, molecular knowledge of the still growing family of collagenous proteins. Its intention is to provide a comprehensive summary of all mechanisms known to be involved in synthesis, processing and deposition of collagen molecules, all of which are apparently shared by any known collagen type as part of a common biosynthetic route. From the intracellular initiation of protein translation to the extracellular deposition of mature molecules into the scaffold of the preformed tissue texture, collagen biosynthesis exhibits a profile of mechanisms absolutely unique when compared to other proteins
Materials Syntheses : A Practical Guide
Materials syntheses are generally more complex than syntheses of inorganic or organic compounds, and specific characterization methods play a more important role. Materials synthesis protocols often suffer from unclarities, irreproducibility, lack in detail and lack in standards. The need to change this situation is the main motivation for this book. A number of detailed protocols has been collected, ranging from organic polymers to carbonaceous and ceramic materials, from gels to porous and layered materials and from powders and nanoparticles to films. Preparation methods include intercalation and flux methods, sol-gel processing, templating methods for porous materials, sonochemistry or spray pyrolysis.
