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Groundwater Geochemistry : A Practical Guide to Modeling of Natural and Contaminated Aquatic Systems
Numerical groundwater flow, transport, and geochemical models are important tools besides classical deterministic and analytical approaches. Solving complex linear or non-linear systems of equations, commonly with hundreds of unknown parameters, is a routine task for a PC. Modeling hydrogeochemical processes requires a detailed and accurate water analysis, as well as thermodynamic and kinetic data as input. Thermodynamic data, such as complex formation constants and solubility-products, are often provided as databases within the respective programs. However, the description of surface-controlled reactions (sorption, cation exchange, surface complexation) and kinetically controlled reactions requires additional input data. Unlike groundwater flow and transport models, thermodynamic models, in principal, do not need any calibration.
Groundwater Geochemistry : A Practical Guide to Modeling of Natural and Contaminated Aquatic Systems
Offers beginners and advanced modellers alike a minimum theoretical background and a focus on the practical solution of geochemical modeling with PHREEQC. This book covers the possibility to use PITZER equation and the CD music concept within the version of PHREEQC.
