الصفحة 9
الصفحة 9
Crystalline cellulose and derivatives : Characterization and structures
Constitutes a valuable, concise and up-to-date guide for the materials and life science community interested in cellulose and related materials. Reliable crystal structures of all cellulose polymorphs and cellulose derivatives determined are critically reviewed and discussed. Models are represented in graphs together with a collection of geometrical data as well as the atomic coordinates for further use. The background for fiber diffraction, computer-aided modeling and spectroscopic investigations is briefly introduced and also included are the necessary molecular data from oligosaccharides as a basis for structure evaluations. X-ray diffraction patterns and spectroscopic diagrams are presented as references to characterize cellulosic materials and to serve as fingerprint tools for the exploration of unknown specimens of cell walls and of industrially processed films and fibers as well as solid-state materials.
Controlled Synthesis of Nanoparticles in Microheterogeneous Systems
contains descriptions of one of the most powerful bottom-up methods of synthesizing size controlled and stable nanoparticles. This method is based on the use of surfactant-containing microheterogeneous systems: liquid crystals, monolayers and multilayers, solutions of direct and reversed micelles, direct and reversed vesicles, and water-in-oil and oil-in-water microemulsions. The author is prominent in the field of physico-chemical characterization of microheterogeneous systems and their use as ideal solvent and reaction media for the production and long-term storage of nanomaterials. This is the first book that attempts to unify the knowledge necessary for judicious manipulation of surfactant-based systems and a fine tuning of geometric and physico-chemical properties of nanoparticles of a wide variety of substances
Computer Simulations of Liquid Crystals and Polymers ; Proceedings of the NATO Advanced Research Workshop on Computational Methods for Polymers and Liquid Crystalline Polymers, Erice, Italy. 16-22 July 2003
Liquid crystals, polymers and polymer liquid crystals are soft condensed matter systems of major technological and scientific interest. An understanding of the macroscopic properties of these complex systems and of their many and interesting peculiarities at the molecular level can nowadays only be attained using computer simulations and statistical mechanical theories. Both in the Liquid Crystal and Polymer fields a considerable amount of simulation work has been done in the last few years with various classes of models at different special resolutions, ranging from atomistic to molecular and coarse-grained lattice models. Each of the two fields has developed its own set of tools and specialized procedures and the book aims to provide a state of the art review of the computer simulation studies of polymers and liquid crystals. This is of great importance in view of a potential cross-fertilization between these connected areas which is particularly apparent for a number of experimental systems like, e.g. polymer liquid crystals and anisotropic gels where the different fields necessarily merge. An effort has been made to assess the possibilities of a coherent description of the themes that have developed independently, and to compare and extend the theoretical and computational techniques put forward in the different areas.
Computer simulations in condensed matter : From materials to chemical biology ; Vol.2
This extensive and comprehensive collection of lectures by world-leading experts in the field introduces and reviews all relevant computer simulation methods and their applications in condensed matter systems. Volume 1, published as LNP 703 (ISBN 3-540-35270-8) is an in-depth introduction to a vast spectrum of computational techniques for statistical mechanical systems of condensed matter. It will enable the graduate student and both the specialist and nonspecialist researcher to get acquainted with the tools necessary to carry out numerical simulations at an advanced level. The present volume is a state-of-the-art survey on numerical experiments carried out for a great number of systems, ranging from materials sciences to chemical biology, such as supercooled liquids, spin glasses, colloids, polymers, liquid crystals, biological membranes and folding proteins.
Computational methods for nanoscale applications : Particles, plasmons and waves
Computational Methods for Nanoscale Applications: Particles, Plasmons and Waves presents new perspectives on modern nanoscale problems where fundamental science meets technology and computer modeling. This book describes well-known computational techniques such as finite-difference schemes, finite element analysis and Ewald summation, as well as a new finite-difference calculus of Flexible Local Approximation MEthods (FLAME) that qualitatively improves the numerical accuracy in a variety of problems. Application areas in the book include long-range particle interactions in homogeneous and heterogeneous media, electrostatics of colloidal systems, wave propagation in photonic crystals, photonic band structure, plasmon field enhancement, and metamaterials with backward waves and negative refraction.
Computational Electronic Circuits : Simulation and Analysis with MATLAB®
This textbook teaches in one, coherent presentation the three distinct topics of analysis of electronic circuits, mathematical numerical algorithms and coding in a software such as MATLAB®. By combining the capabilities of circuit simulators and mathematical software, the author teaches key concepts of circuit analysis and algorithms, using a modern approach. The DC, Transient, AC, Noise and behavioral analyses are implemented in MATLAB to study the complete characteristics of a variety of electronic circuits, such as amplifiers, rectifiers, hysteresis circuits, harmonic traps and passes, polyphaser filters, directional couplers, electro-static discharge and piezoelectric crystals. This book teaches basic and advanced circuit analysis, by incorporating algorithms and simulations that teach readers how to develop their own simulators and fully characterize and design electronic circuits.
Cloud Optics
Clouds affect the climate of the Earth, and they are an important factor in the weather. Therefore, their radiative properties must be understood in great detail. This book summarizes current knowledge on cloud optical properties, for example their ability to absorb, transmit, and reflect light, which depends on the clouds’ geometrical and microphysical characteristics such as sizes of droplets and crystals, their shapes, and structures. In addition, problems related to the image transfer through clouds and cloud remote sensing are addressed in this book in great detail. This book can be an important source of information on theoretical cloud optics for cloud physicists, meteorologists and optical engineers.
Materials for Tomorrow : Theory, Experiments and Modelling
This book contains six chapters on central topics in materials science. Each is written by specialists in the field, and gives a state-of-the-art presentation of the subject for graduate students and scientists not necessarily working in that field. Computer simulations of new materials, theory and experimental work are all extensively discussed. As nanomaterials are of great current interest, most of the topics discussed have a bearing on nanomaterials and nanodevices. In addition to inorganic nanotubes, metallic nanocrystals, electronic nanodevices, spintronics and interfaces on an atomic scale, the text also presents computer simulations on one of the less well understood fields in solid-state physics and materials science: glasses and undercooled fluids.
Magnetoreception and Magnetosomes in Bacteria
Recent developments in the research on magnetotactic bacteria are presented in this volume. Included are reviews on the formation and organization of magnetosomes, the genes controlling magnetosome biomineralization, and new cryogenic techniques to visualize novel cytoskeleton structures. Described here are potential nanobiotechnological applications of the magnetosome crystals, which have magnetic and crystalline characteristics unmatched by their inorganic counterparts.
Magnetohydrodynamics : Historical Evolution and Trends
Magnetohydrodynamics (MHD) studies the interaction between the flow of an electrically conducting fluid and magnetic fields. It involves such diverse topics as the evolution and dynamics of astrophysical objects, thermonuclear fusion, metallurgy and semiconductor crystal growth, etc. Although the first ideas in magnetohydrodynamics appeared at the beginning of the last century, the "explosion" in theoretical and experimental studies occurred in the 1950s-60s. This state-of-the-art book aims at revising the evolution of ideas in various branches of magnetohydrodynamics (astrophysics, earth and solar dynamos, plasmas, MHD turbulence and liquid metals) and reviews current trends and challenges.
Magnetic Functions Beyond the Spin-Hamiltonian
Using the spin-Hamiltonian formalism the magnetic parameters are introduced through the components of the Lambda-tensor involving only the matrix elements of the angular momentum operator. The energy levels for a variety of spins are generated and the modeling of the magnetization, the magnetic susceptibility and the heat capacity is done. Theoretical formulae necessary in performing the energy level calculations for a multi-term system are prepared with the help of the irreducible tensor operator approach. The goal of the programming lies in the fact that the entire relevant matrix elements (electron repulsion, crystal field, spin-orbit interaction, orbital-Zeeman, and spin-Zeeman operators) are evaluated in the basis set of free-atom terms. The modeling of the zero-field splitting is done at three levels of sophistication. The spin-Hamiltonian formalism offers simple formulae for the magnetic parameters by evaluating the matrix elements of the angular momentum operator in the basis set of the crystal-field terms. The magnetic functions for dn complexes are modeled for a wide range of the crystal-field strengths.
Low Thermal Expansion Glass Ceramics
Describes the fundamental principles, the manufacturing process, and applications of low thermal expansion glass ceramics. The composition, structure, and stability of polycrystalline materials having a low thermal expansion are described, and it is shown how low thermal expansion glass ceramics can be manufactured from appropriately chosen glass compositions. Examples illustrate the formation of this type of glass ceramic by utilizing normal production processes together with controlled crystallization. Thus glass ceramics with thermal coefficients of expansion of less than 0.3 x 10(-6)K(-1) can be obtained. Even for the mass production of high-quality cooktop panels (Ceran®., oven windows, and other household appliances a high reproducibility of the properties is achieved. Special glass ceramics (Zerodur®. for technological and scientific applications such as high-precision optics or large astronomical mirrors are likewise discussed. The completely revised edition also features new sections on glass-ceramic applications, with details on their performance, CDC-grinding, and laser gyroscopes containing Zerodur®..
Low Molecular Mass Gelators : Design, Self-Assembly, Function
Chapter 1 presents the physical principles of the growth mechanism of fiber and fiber network with LMGs, as treated on the basis of the heterogeneous nucleation model. in Chaps. 2 and 3, respectively. These chapters are intended to outline useful synthetic guidelines for the generation of an ever-increasing variety of molecular architectures within these two families of gelators. Recent developments in the chemistry of nucleobase-containing LMGs are described in Chap. 4. Hydrogen-bonding within these molecular systems involves complementary base pair formation, a process relevant to DNA double-helix formation The self-assembly of chiral organo- or hydrogelators is the subject of Chap. 5. result from the orthogonal self-assembly of liquid crystals and LMGs are presented in Chap. 6. The volume concludes with Chap. 7, a review of the emerging field of dendritic gels.
Liquid Crystalline Functional Assemblies and Their Supramolecular Structures
This book presents critical reviews of the present position and future trends in modern chemical research concerned with chemical structure and bonding. It contains short and concise reports, each written by the world's renowned experts.
Linearity, Symmetry, and Prediction in the Hydrogen Atom
The predictive power of mathematics in quantum phenomena is one of the great intellectual successes of the 20th century. This textbook, aimed at undergraduate or graduate level students (depending on the college or university), concentrates on how to make predictions about the numbers of each kind of basic state of a quantum system from only two ingredients: the symmetry and the linear model of quantum mechanics. This method, involving the mathematical area of representation theory or group theory, combines three core mathematical subjects, namely, linear algebra, analysis and abstract algebra. Wide applications of this method occur in crystallography, atomic structure, classification of manifolds with symmetry, and other areas.
Light-Associated Reactions of Synthetic Polymers
This book presents a range of reactions and materials with some of the most exciting current and future applications. It includes a brief introduction to photochemistry; in-depth discussion of photosensitizers, photoinititiators, and the processes of light curing and crosslinking; listing of light responsive polymers and their uses; and a discussion of polymeric materials for use in non-linear optics.
Let's talk : How English conversation works
Banter, chit-chat, gossip, natter, tete-a-tete: these are just a few of the terms for the varied ways in which we interact with one another through conversation. David Crystal explores the factors that motivate so many different kinds of talk and reveals the rules we use unconsciously, even in the most routine exchanges of everyday conversation. We tend to think of conversation as something spontaneous, instinctive, habitual.
Laser Ablation and its Applications
Laser Ablation and its Applications emphasizes the wide range of these topics rather than focusing on one specialty or discipline. It is intended for a graduate course in laser interactions with plasmas and materials, but it should be accessible to anyone with a graduate degree in physics or engineering.
Kinetics of Catalytic Reactions--Solutions Manual
This textbook contains all the information needed for graduate students or industrial researchers to design kinetic experiments involving heterogeneous catalysts, to characterize these catalysts, to acquire valid rate data, to verify the absence of mass (and heat) transfer limitations, to propose reaction models, to derive rate expressions based on these models and, finally, to assess the consistency of these rate equations.The most recent technique to calculate heats of adsorption and activation barriers on metal surfaces, the BOC-MP approach, is discussed in detail. Methods to measure metal surface areas and crystallite sizes using x-ray diffraction, transmission electron microscopy and various chemisorption techniques are discussed. Different experimental techniques to determine the influence of mass transfer limitations, especially within the pores of a catalyst, are reviewed in detail, with a particular emphasis on liquid-phase reactions.
Kinetics of Catalytic Reactions
This textbook contains all the information needed for graduate students or industrial researchers to design kinetic experiments involving heterogeneous catalysts, to characterize these catalysts, to acquire valid rate data, to verify the absence of mass (and heat) transfer limitations, to propose reaction models, to derive rate expressions based on these models and, finally, to assess the consistency of these rate equations.Many illustrations of these and other topics are provided along with numerous problems and a Solutions Manual for instructors. This book will be applicable to any graduate course in chemical engineering, chemistry or materials science that involves kinetics of catalytic reactions, including those catalyzed by enzymes.
