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this diverse collection of topics gives a sampling of the very sophisticated and powerful methodologies utilized in the construction of complex organic small molecules using radical intermediates. Consistently, the focus is on the newest advances in the field, highlighting very recent works while providing references to valuable reviews of previous work. In a few of the early chapters, the specifics are hard to follow in instances where details are discussed but no structures are provided. However this failing only occurs in a few cases; most of the work is clearly illustrated. This Collection of thoughtfully written chapters serves to highlight the impressive efficiency and selectivity of free-radical chemistry as a powerful and rapidly developing field.