The Inorganic Radiochemistry of Heavy Elements
Publication year: 2008
ISBN: 978-1-4020-6602-3
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The aim of this book is to facilitate the wider use of advantageous gas phase techniques towards heavy elements. Studies of the transactinoid elements (polyvalent metals) stimulated application of their volatile halides, oxides, and oxyhalides to fast radiochemical separations. Selected results are presented here. Primarily, this book features the physico-chemical basis of experimental methods and techniques. It focuses on evaluation of the desorption energy from data of a single gas-solid chromatography experiment through calculation of desorption entropy. Heterogeneity of the column surface and its chemical modification are taken into account.
Subject: Chemistry and Materials Science, Radiochemistry, desorption energies, gas-solid chromatography, heavy metals, thermochemical chromatography, thermochemistry, thermodynamics, transactinide elements
