الصفحة 1
الصفحة 1
One Hundred Years of Chemical Warfare : Research, Deployment, Consequences
On April 22, 1915, the German military released 150 tons of chlorine gas at Ypres, Belgium. Carried by a long-awaited wind, the chlorine cloud passed within a few minutes through the British and French trenches, leaving behind at least 1,000 dead and 4,000 injured. This chemical attack, which amounted to the first use of a weapon of mass destruction, marks a turning point in world history. The preparation as well as the execution of the gas attack was orchestrated by Fritz Haber, the director of the Kaiser Wilhelm Institute for Physical Chemistry and Electrochemistry in Berlin-Dahlem. During World War I, Haber transformed his research institute into a center for the development of chemical weapons (and of the means of protection against them).
Modern Aspects of Electrochemistry ; Vol. 42
MODERN ASPECTS OF ELECTROCHEMISTRY No. 42 Edited by Constantinos Vayenas University of Patras, Greece Topics in Number 42 include: The electrochemistry and electrocatalysis of Ruthenium in regards to the development of electrodes for Polymer Electrolyte Membrane (PEM) fuel cells Breakthroughs in Solid Oxide Fuel Cell (SOFC) anodes and cathodes leading to improved electrocatalysis Electrocatalysis of the electrochemical reduction of CO2 on numerous metals The interfacial phenomena of electrodeposition and codeposition, and the need for new theoretical analyses of the electrode-electrolyte interface Advantages of scanning tunneling microscopy (STM) in understanding the basics of catalysis, electrocatalysis and electrodeposition The role of electrochemistry in emerging technologies including electrodeposition and electroforming at the micro and nano levels, semiconductor and information storage, including magnetic storage devices.
Modern Aspects of Electrochemistry ; Vol. 41
The 41st volume in this series covers a range of topics that touch on issues of potential interest to those working in electrochemistry-related fields. … Overall, this text contains a diverse collection of topics that would be of varying degrees of interest to the broader electrochemistry community. More likely, the individual chapters would be most valued by specialists working in these areas."As the most recent volume of a successful series established 1954 and carefully continued this book provides a timely collection of four review papers covering widely distributed aspects of electrochemistry in representative contributions.
Modern Aspects of Electrochemistry ; Vol. 39
This volume of Modern Aspects covers a wide spread of topics presented in an authoritative, informative and instructive manner by some internationally renowned specialists. Professors Politzer and Dr. Murray provide a comprehensive description of the various theoretical treatments of solute-solvent interactions, including ion-solvent interactions. Both continuum and discrete molecular models for the solvent molecules are discussed, including Monte Carlo and molecular dynamics simulations. The advantages and drawbacks of the resulting models and computational approaches are discussed and the impressive progress made in predicting the properties of molecular and ionic solutions is surveyed.
Modern Aspects of Electrochemistry ; Vol. 38
Solid State Electrochemistry encompassing modern equilibria concepts, thermodymanics and kinetics of charge carriers in solids.,Electron transfer processes, with special sections devoted to hydration of the proton and its heterogeneous transfer.Electrosorption at electrodes and its relevance to electrocatalysis and electrodeposition of metals,The behavior of Pt and other alloy electrocatalyst crystallites used as the electrode materials for phosphoric acid electrolyte fuel-cells.Applications of reflexology and electron microscopy to the materials science aspect of metal electrodes.Electroplating of metal matrix composites by codeposition of suspended particles, a process that has improved physical and electrochemical properties.
Mini-Micro Fuel Cells : Fundamentals and Applications
This volume contains an archival record of the NATO Advanced Institute on Mini – Micro Fuel Cells – Fundamental and Applications held in Çesme – Izmir, Turkey, July 22–August 3, 2007. The ASIs are intended to be a high-level teaching activity in scientific and technical areas of current concern. In this volume, the reader may find interesting chapters on Mini- Micro Fuel Cells with fundamentals and applications. In recent years, fu- cell development, modeling and performance analysis has received much attention due to their potential for distributed power which is a critical issue for energy security and the environmental protection.
Interfacial Nanochemistry : Molecular Science and Engineering at Liquid-Liquid Interfaces
The presence of liquid-liquid interface means that real liquids are far from ideal liquids that must be miscible with any kinds of liquids and have no interface. Thus it can be said that the non-ideality of liquids might generate the liquid-liquid interface indeed and that biological systems might be generated from the non-ideal interface. The liquid-liquid interface has been, therefore, studied as a model of biological membrane. From pairing two-phases of gas, liquid and solid, nine different pairs can be obtained, which include three homo-pairs of gas-gas, liquid-liquid and solid-solid pairs. The gas-gas interface, however, is practically no use under the ordinary conditions. Among the interfaces produced by the pairing, the liquid-liquid interface is most slippery and difficult to be studied experimentally in comparison with the gas-liquid and solid-liquid interfaces, as the liquid-liquid interface is flexible, thin and buried between bulk liquid phases. Therefore, in order to study the liquid-liquid interface, the invention of innovative measurement methods has a primary importance.
ICAME 2005 ; Proceedings of the 28th International Conference on the Applications of the Mössbauer Effect (ICAME 2005) held in Montpellier, France, 4–9 September 2005, Vol. I (Part I–II/V)
This book provides an up-to-date overview of the Mössbauer effect in physics, chemistry, electrochemistry, catalysis, biology, medicine, geology, mineralogy, archaeology and materials science.
Hydrogen Technology : Mobile and Portable Applications
This book presents the current state of the hydrogen economy with the focus on applications in the automotive technology and industry - Where are we in the implementation of hydrogen economy? What are the perspectives? Which are the directions to develop this field? This book answers these questions by compiling reviews from internationally recognized researchers.
Handbook of Chlor-Alkali Technology ; Vol. I : Fundamentals ; Vol. II : Brine Treatment and Cell Operation ; Vol. III : Facility Design and Product Handling ; Vol. IV : Operations ; Vol. V : Corrosion, Environmental Issues, and Future Developments
The book explores the basic electrode processes and the fundamentals of current distribution in electrolyzers as well as the characteristics of the leading cell designs while the appendix offers selected physical property data. The authors, each with extensive experience in chlor-alkali technology but with diverse backgrounds and fields of specialization, achieve both breadth and depth. Anyone with interest in the large field of chlor-alkali manufacture and distribution, and indeed in industrial electrochemistry in general, will find something useful here. The Handbook offers not only broad coverage, but also in depth treatment of each topic. It will be an asset to managers, process engineers and operating personnel working in the chlor-alkali industry. This book provides valuable information to engineers and scientists involved in development of chlor-alkali technology and in the design of new plant or upgrading of existing plants. It will be especially valuable to universities as it begins with fundamentals and progresses methodically throu gh each step involved in chlor-alkali production, including environmental issues.
Fuel Cells II
The concept to utilize an ion-conducting polymer membrane as a solid po- mer electrolyte offers several advantages regarding the design and operation of an electrochemical cell, as outlined in Volume 215, Chapter 1 (L. Gubler, G.G. Scherer). Essentially, the solvent and/or transport medium, e.g., H O, 2 + for the mobile ionic species, e.g., H for a cation exchange membrane, is taken up by and con?ned into the nano-dimensional morphology of the i- containingdomainsofthepolymer.Asaconsequence, aphaseseparationinto a hydrophilic ion-containing solvent phase and a hydrophobic polymer ba- bone phase establishes. Because of the narrow solid electrolyte gap in these cells, low ohmic losses reducing the overall cell voltage can be achieved, even at highcurrent densities.
Fuel Cells I
The concept to utilize an ion-conducting polymer membrane as a solid po- mer electrolyte offers several advantages regarding the design and operation of an electrochemical cell, as outlined in Volume 215, Chapter 1 (L. Gubler, G.G. Scherer). Essentially, the solvent and/or transport medium, e.g., H O, 2 + for the mobile ionic species, e.g., H for a cation exchange membrane, is taken up by and con?ned into the nano-dimensional morphology of the i- containingdomainsofthepolymer.Asaconsequence, aphaseseparationinto a hydrophilic ion-containing solvent phase and a hydrophobic polymer ba- bone phase establishes. Because of the narrow solid electrolyte gap in these cells, low ohmic losses reducing the overall cell voltage can be achieved, even at highcurrent densities.
Fuel Cells : From Fundamentals to Applications
Fuel Cells: Fundamentals to Applications is a concise source of the basic electrochemical principles and engineering aspects involved in the development and commercialization of fuel cells. It describes the applications and techno-economic assessment of fuel cell technologies along with an in-depth discussion of conventional and novel approaches pursued for generating energy. This book is divided into four parts. Parts I and II explain basic and applied electrochemistry relevant to an understanding of fuel cells. Part III covers engineering and technology aspects and Part IV, applications and economics. The first part covers, in detail, the electrode kinetics and electrocatalysis of charge-transfer reactions, and leading electrochemical technologies with focus on relevance to fuel cells. The second part addresses the governing principles of fuel cells, electrocatalysis of fuel cell reactions and experimental techniques pertinent to fuel cell research and development. The third part is devoted to modeling of fuel cell systems and a thorough discussion of fuels, fuel processing and fuel storage, transmission, and distribution. The final part deals with the status of the fuel cell technologies, their applications and economics.
Ferro- and Antiferroelectricity : Order/Disorder versus Displacive
Solid-state systems are frequently classi?ed according to their physical, str- tural or chemical properties. Such schemes are extremely helpful since pr- erties related to any such classi?cation are typically known and facilitate id- tifying solids with special material classes. The best-known examples of these schemes are conductivity or resistivity measurements by means of which m- als are easily distinguishable from insulators. However, frequently clear-cut decisions between material classes are not possible, since anisotropy, chemical composition, binding forces and local effects wash out distinct properties and lead to competition or coexistence. Such unresolved situations are especially typical for transition metal oxides that exhibit a variety of ground-state properties in a fascinating way.
Electrochemistry of Immobilized Particles and Droplets
Immobilizing particles or droplets on electrodes is a novel and most powerful technique for studying the electrochemical reactions of three-phase systems. It gives access to a wealth of information, ranging from quantitative and phase analysis to thermodynamic and kinetic data of electrode processes. Three-phase electrodes with immobilized droplets provide information on the electrochemistry of redox liquids and of compounds dissolved in inert organic liquids. Such measurements allow the determination of the Gibbs energies of the transfer of cations and anions between immiscible solvents, and thus make it possible to assess the hydrophobicity of ions – a property that is of great importance for pharmaceutical applications, biological studies, and for many fields of chemistry.The monograph gives, for the first time, a comprehensive overview of the results published in more than 300 papers over the last 15 years. The experiments are explained in detail, applications from many different fields are presented, and the theoretical basis of the systems is outlined.
Electrochemical Dictionary
The Electrochemical Dictionary provides up-to-date, broad and authoritative coverage of the specific terms most used in electrochemistry and its related fields, including relevant areas of physics and engineering. This modern compendium will be an indispensable source of information for scientists, engineers, and technical staff active in all fields of electrochemistry. The more than 2.770 entries have been written by a distinguished panel of eminent electrochemists. Each entry supplies a clear and precise explanation of the term and provides references to the most useful reviews, books and original papers to enable readers to pursue a deeper understanding if so desired.
Digital Simulation in Electrochemistry
The book shows how to numerically solve the parabolic partial differential equations (pdes) encountered in electroanalytical chemistry. It does this in a didactic manner, by first introducing the basic equations to be solved and some model systems as text cases, for which solutions exist. Then it treats basic numerical approximation for derivatives and techniques for the numerical solution of ordinary differential equations, from which the more complicated methods for pdes can be derived. The major implicit methods are described in detail, and the handling of homogeneous chemical reactions, including coupled and nonlinear cases, is detailed. More advanced techniques are presented briefly, as well as some commercially available program packages.
Deep eutectic polvents : Synthesis, properties, and applications
Deep Eutectic Solvents contains a comprehensive review of the use of deep eutectic solvents (DESs) as an environmentally benign alternative reaction media for chemical transformations and processes. The contributors cover a range of topics including synthesis, structure, properties, toxicity and biodegradability of DESs. The book also explores myriad applications in various disciplines, such as organic synthesis and (bio)catalysis, electrochemistry, extraction, analytical chemistry, polymerizations, (nano)materials preparation, biomass processing, and gas adsorption.
Conducting Polymers : A New Era in Electrochemistry
The discovery of polymers with variable conductivity brought forth a paradigmatic change in chemistry and in other branches of science and technology. Electrochemistry has played a central role in the preparation, characterization and application of these new materials. This book is a systematic survey of the knowledge accumulated in this field in the last thirty years. It includes thermodynamic aspects, the theory of the mechanism of charge transport processes, the chemical and physical properties of these compounds, the techniques of characterization, the chemical and electrochemical methods of synthesis as well as the application of these systems. The book contains a compilation of the polymers prepared so far and covers the relevant literature.
Characterization of Corrosion Products on Steel Surfaces
It is well known that corrosion products, i.e. rust, on iron and steel surfaces cannot be assigned a typical crystallographic structure with long-range order. In fact, the structure of rust is considered to be very complicated, and some forms of rust are assigned to the amorphous state for this reason. Accurate information about the atomic-scale structure of rust is important to shed light on corrosion mechanisms of metallic materials. And, since life of steel structures is often dominated by environmental degradation or corrosion of the surface, the structure of the rust formed on iron and steel surfaces during prolonged exposure to air is of great interest. This book describes the fundamental aspects of materials characterization for the ferric oxyhydroxides formed on steel surfaces.
